| Central Research and Development Activities
The Johnson Matthey Technology Centre (JMTC) is the
group’s central resource for longer term research and employs
over 180 world class scientists. It supports the research and development
of new products and technology across all of Johnson Matthey’s
businesses and has expertise in catalysis, precious metals, materials
science and many other fields in which Johnson Matthey operates.
JMTC has state of the art facilities and resources
for the development and testing of catalysts as well as one of the
most advanced analytical science groups in the world, equipped with
the latest tools for materials characterisation.
Collaboration is important and JMTC works closely
with the group’s global network of business specific technology
centres and development groups. It also participates in external
collaborative research and development programmes worldwide.
Many projects at JMTC are sponsored by the operating
divisions to meet their longer term objectives alongside which run
a number of core science projects to address the fundamental science
that lies at the heart of many of our businesses. Our core science
projects also address sustainability issues such as energy efficiency,
waste reduction, resource thrifting and low carbon technology. These
projects focus on improving the sustainability performance of our
own operations and on developing the next generation of sustainable
products and technologies for our customers. Knowledge gained in
the core science programmes is used to accelerate and improve product
development across the group, reducing time to market and improving
our ability to design products to meet customers’ needs.
Materials characterisation is a key component of all
our R&D programmes. We have state of the art facilities and
unique expertise in house as well as access to some of the world’s
most advanced equipment. These techniques provide us with an insight
into the structure of materials at an atomic level which gives us
the ability to relate the chemical structure of our products to
their performance. This provides knowledge and information which
is vital to the design and optimisation of new and enhanced products
for our customers.
Three examples of how this approach is being used
to deliver advanced new catalysts for the Environmental Technologies
Division are outlined below.
Fischer Tropsch Chemistry at the Nano Scale
Fischer Tropsch (FT) catalysis is a key step in gas to liquids (GTL)
processes and will be a key enabler in the conversion of coal and
biomass to liquid fuels. Although FT catalysis was discovered nearly
one hundred years ago, 21st century applications will require the
design of catalysts with specific functionalities. Johnson Matthey
has pioneered the use of advanced characterisation techniques to
examine the structure of FT catalysts from micron scale catalyst
particles right through to individual atoms at the nano scale.
Using our in house expertise and working in collaboration
with world leading academic groups, Johnson Matthey has been able
to fully characterise FT catalysts at the nano scale. This detailed
understanding is enabling us to assist customers in the design of
advanced FT catalyst systems with specific functionalities, tailored
to their individual requirements.
Fuel Cell Catalyst Design
In fuel cell catalysts, the specific arrangement of surface and
bulk atoms holds the key to optimising catalytic activity and selectivity.
Determining the detailed structure of catalyst particles is therefore
fundamental to developing the optimum fuel cell catalyst. Johnson
Matthey has been working in collaboration with a number of academic
partners to study the arrangement of atoms within individual fuel
cell catalyst particles. Advanced techniques such as solid state
nuclear magnetic resonance and x-ray absorption spectroscopy have
been used to provide vital information about the arrangement of
atoms and their nearest neighbours. In addition a specially designed
fuel cell allows us to characterise catalysts in situ under realistic
operating conditions. Scientific knowledge gained from these advanced
techniques will enable Johnson Matthey to design and manufacture
optimum fuel cell catalysts of the future.
Advanced Characterisation of Autocatalysts
Johnson Matthey’s Emission Control Technologies business manufactures
platinum group metal (pgm) containing catalyst systems to remove
harmful pollutants from automotive exhausts. Catalysts must perform
to meet legislated limits for exhaust emissions but must also have
the durability and longevity to operate effectively under the harsh
operating conditions of a vehicle.
Understanding how and why these catalysts deactivate
over time is key to the manufacture of the next generation of highly
active, highly durable products. Deactivation of the catalyst is
usually due to a reduction in surface area of the active metal species
caused by particle size enlargement. At JMTC we are using our characterisation
expertise to examine the sizes of pgm nanoparticles in autocatalysts
and the routes by which they intermix over time.
In our laboratories we subject catalysts to accelerated
ageing and use a range of advanced techniques to characterise the
aged materials. The data obtained enables us to examine and understand
how metal particles aggregate over time. This in turn can be related
to catalyst performance. Further developing our understanding of
the relationship between metal particle aggregation and catalyst
ageing enables us to design more effective products for our customers.
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